In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode

doi:10.1016/j.jechem.2017.05.004

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (6): 1140-1146.DOI: 10.1016/j.jechem.2017.05.004

In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode

Yanghua He^a, Jinming Xu^a, Fanan Wang^a,b, Xiaochen Zhao^a, Guangzhao Yin^c, Qing Mao^c, Yanqiang Huang^a, Tao Zhang^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

收稿日期:2017-03-09 修回日期:2017-05-24 出版日期:2017-11-15 发布日期:2017-11-24
通讯作者: Qing Mao,E-mail addresses:maoqing@dlut.edu.cn;Yanqiang Huang,E-mail addresses:yqhuang@dicp.ac.cn
基金资助:
The authors acknowledge the support of the National Natural Science Foundation of China (21403218, 21476226, 21403029), Ministry of Science and Technology of the People's Republic of China under contact of 2016YFA0202800 and the Youth Innovation Promotion Association of the CAS, the Scientific Research Project of the Education Department of Liaoning Province (L2014022); the Fundamental Research Funds for the Central Universities (DUT15ZD225).

In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode

Yanghua He^a, Jinming Xu^a, Fanan Wang^a,b, Xiaochen Zhao^a, Guangzhao Yin^c, Qing Mao^c, Yanqiang Huang^a, Tao Zhang^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Chemical Engineering, Dalian University of Technology, Dalian 116024, Liaoning, China

Received:2017-03-09 Revised:2017-05-24 Online:2017-11-15 Published:2017-11-24
Contact: Qing Mao,E-mail addresses:maoqing@dlut.edu.cn;Yanqiang Huang,E-mail addresses:yqhuang@dicp.ac.cn
Supported by:
The authors acknowledge the support of the National Natural Science Foundation of China (21403218, 21476226, 21403029), Ministry of Science and Technology of the People's Republic of China under contact of 2016YFA0202800 and the Youth Innovation Promotion Association of the CAS, the Scientific Research Project of the Education Department of Liaoning Province (L2014022); the Fundamental Research Funds for the Central Universities (DUT15ZD225).

摘要/Abstract

摘要： A binder-free Ir-dispersed ordered mesoporous carbon (Ir-OMC) catalytic electrode has been prepared through a designed in-situ carbonization method, which involves coating resorcinol and formaldehyde mixtures with iridium precursors onto the three-dimensional nickel foam framework, followed by insitu calcination in N₂ atmosphere at 800℃ for 3 h. This electrode shows a large surface area, ordered mesoporous structure and homogeneous distribution of metal nanoparticles. It presents good activity and stability towards hydrogen evolution reaction, which is attributed to the efficient mass and electron transport from the intimate contact among Ir nanoparticles, ordered mesoporous carbon matrix and 3D conductive substrate. We hope that this in-situ carbonization synthetic route can also be applied to design more high-performance catalysts for water splitting, fuel cells and other clean energy devices.

关键词: In-situ carbonization, Ordered mesoporous carbon, HER

Abstract: A binder-free Ir-dispersed ordered mesoporous carbon (Ir-OMC) catalytic electrode has been prepared through a designed in-situ carbonization method, which involves coating resorcinol and formaldehyde mixtures with iridium precursors onto the three-dimensional nickel foam framework, followed by insitu calcination in N₂ atmosphere at 800℃ for 3 h. This electrode shows a large surface area, ordered mesoporous structure and homogeneous distribution of metal nanoparticles. It presents good activity and stability towards hydrogen evolution reaction, which is attributed to the efficient mass and electron transport from the intimate contact among Ir nanoparticles, ordered mesoporous carbon matrix and 3D conductive substrate. We hope that this in-situ carbonization synthetic route can also be applied to design more high-performance catalysts for water splitting, fuel cells and other clean energy devices.

Key words: In-situ carbonization, Ordered mesoporous carbon, HER

Yanghua He, Jinming Xu, Fanan Wang, Xiaochen Zhao, Guangzhao Yin, Qing Mao, Yanqiang Huang, Tao Zhang. In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode[J]. 能源化学(英文), 2017, 26(6): 1140-1146.

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In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode

In-situ carbonization approach for the binder-free Ir-dispersed ordered mesoporous carbon hydrogen evolution electrode

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