Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

doi:10.1016/j.jechem.2017.06.013

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (6): 1174-1180.DOI: 10.1016/j.jechem.2017.06.013

Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

Yifan Ye^a,b, Fan Cai^a,b, Chengcheng Yan^a,b, Yanshuo Li^c, Guoxiong Wang^a, Xinhe Bao^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, China

收稿日期:2017-05-31 修回日期:2017-06-29 出版日期:2017-11-15 发布日期:2017-11-24
通讯作者: Guoxiong Wang,E-mail addresses:wanggx@dicp.ac.cn;Xinhe Bao,E-mail addresses:xhbao@dicp.ac.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (Grants 21573222, 21622607, 91545202 and U1532117), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB17020200), CAS Youth Innovation Promotion and K. C. Wong Education Foundation in Ningbo University.

Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

Yifan Ye^a,b, Fan Cai^a,b, Chengcheng Yan^a,b, Yanshuo Li^c, Guoxiong Wang^a, Xinhe Bao^a

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
b University of Chinese Academy of Sciences, Beijing 100049, China;
c School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, Zhejiang, China

Received:2017-05-31 Revised:2017-06-29 Online:2017-11-15 Published:2017-11-24
Contact: Guoxiong Wang,E-mail addresses:wanggx@dicp.ac.cn;Xinhe Bao,E-mail addresses:xhbao@dicp.ac.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Grants 21573222, 21622607, 91545202 and U1532117), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB17020200), CAS Youth Innovation Promotion and K. C. Wong Education Foundation in Ningbo University.

摘要/Abstract

摘要： Zeolitic imidazolate frameworks (ZIFs) are widely employed in catalyst synthesis as parental materials for electrochemical energy storage and conversion. Herein, we have demonstrated a facile synthesis of highly efficient catalyst for oxygen reduction reaction in both alkaline and acidic medium, which is derived from ZIF-8 functionalized with ammonium ferric citrate via two-step pyrolysis in Ar and NH₃ atmosphere. The results reveal that the catalytic activity improvement after NH₃ pyrolysis benefits from mesoporedominated morphology and high utilization of Fe-containing active sites. The optimum catalyst shows excellent performance in zinc-air battery and polymer electrolyte membrane fuel cell tests.

关键词: Zeolitic imidazolate frameworks, Two-step pyrolysis, Oxygen reduction reaction, Zinc-air battery, Polymer electrolyte membrane fuel cell

Abstract: Zeolitic imidazolate frameworks (ZIFs) are widely employed in catalyst synthesis as parental materials for electrochemical energy storage and conversion. Herein, we have demonstrated a facile synthesis of highly efficient catalyst for oxygen reduction reaction in both alkaline and acidic medium, which is derived from ZIF-8 functionalized with ammonium ferric citrate via two-step pyrolysis in Ar and NH₃ atmosphere. The results reveal that the catalytic activity improvement after NH₃ pyrolysis benefits from mesoporedominated morphology and high utilization of Fe-containing active sites. The optimum catalyst shows excellent performance in zinc-air battery and polymer electrolyte membrane fuel cell tests.

Key words: Zeolitic imidazolate frameworks, Two-step pyrolysis, Oxygen reduction reaction, Zinc-air battery, Polymer electrolyte membrane fuel cell

Yifan Ye, Fan Cai, Chengcheng Yan, Yanshuo Li, Guoxiong Wang, Xinhe Bao. Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction[J]. 能源化学(英文), 2017, 26(6): 1174-1180.

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Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

Two-step pyrolysis of ZIF-8 functionalized with ammonium ferric citrate for efficient oxygen reduction reaction

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