Integrated Ni2P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation

doi:10.1016/j.jechem.2017.07.016

能源化学(英文) ›› 2017, Vol. 26 ›› Issue (6): 1196-1202.DOI: 10.1016/j.jechem.2017.07.016

Integrated Ni₂P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation

Jintao Ren^a,b, Zhongpan Hu^a,b, Chong Chen^a,b, Yuping Liu^b, Zhongyong Yuan^a,b

a National Institute for Advanced Materials, School of Materials Science and Engineering, Nankai University, Tianjin 300353, China;
b Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China

收稿日期:2017-05-12 修回日期:2017-07-24 发布日期:2017-11-24
通讯作者: Zhongyong Yuan,E-mail address:zyyuan@nankai.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21421001, 21573115), and the Natural Science Foundation of Tianjin (17JCYBJC17100).

Integrated Ni₂P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation

Jintao Ren^a,b, Zhongpan Hu^a,b, Chong Chen^a,b, Yuping Liu^b, Zhongyong Yuan^a,b

a National Institute for Advanced Materials, School of Materials Science and Engineering, Nankai University, Tianjin 300353, China;
b Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Nankai University, Tianjin 300071, China

Received:2017-05-12 Revised:2017-07-24 Published:2017-11-24
Contact: Zhongyong Yuan,E-mail address:zyyuan@nankai.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21421001, 21573115), and the Natural Science Foundation of Tianjin (17JCYBJC17100).

摘要/Abstract

摘要： The large-scale synthesis of efficient nonprecious bifunctional electrocatalysts for overall water splitting is a great challenge for future renewable energy conversion systems. Herein, Ni₂P nanosheet arrays directly grown on three-dimensional (3D) Ni foam (NiP/NF) are fabricated by hydrothermal treatment of metallic Ni foam with H₂O₂ solution and subsequent phosphidation with NaH₂PO₂. The NiP/NF as electrocatalyst exhibits superior activities for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Most importantly, employing both as the cathode and anode for an alkaline water electrolyzer, NiP/NF only requires a cell voltage of 1.63 V to reach a current density of 10 mV cm^-2, together with stronger durability. Preliminary catalytic information suggests that the tailored 3D superstructure and integrated electrode configurations afford improved active sties and enhanced electron/mass transfer, responding for the outstanding activity and stability.

关键词: Nickel phosphide, Electrocatalyst, Hydrogen evolution, Oxygen evolution, Water splitting

Abstract: The large-scale synthesis of efficient nonprecious bifunctional electrocatalysts for overall water splitting is a great challenge for future renewable energy conversion systems. Herein, Ni₂P nanosheet arrays directly grown on three-dimensional (3D) Ni foam (NiP/NF) are fabricated by hydrothermal treatment of metallic Ni foam with H₂O₂ solution and subsequent phosphidation with NaH₂PO₂. The NiP/NF as electrocatalyst exhibits superior activities for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Most importantly, employing both as the cathode and anode for an alkaline water electrolyzer, NiP/NF only requires a cell voltage of 1.63 V to reach a current density of 10 mV cm^-2, together with stronger durability. Preliminary catalytic information suggests that the tailored 3D superstructure and integrated electrode configurations afford improved active sties and enhanced electron/mass transfer, responding for the outstanding activity and stability.

Key words: Nickel phosphide, Electrocatalyst, Hydrogen evolution, Oxygen evolution, Water splitting

Jintao Ren, Zhongpan Hu, Chong Chen, Yuping Liu, Zhongyong Yuan. Integrated Ni₂P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation[J]. 能源化学(英文), 2017, 26(6): 1196-1202.

参考文献

[1] Y. Li, R. Jin, Y. Xing, J. Li, S. Song, X. Liu, M. Li, R. Jin, Adv. Energy Mater. 6(2016) 1601273.

[2] H. Shi, H. Liang, F. Ming, Z. Wang, Angew. Chem. Int. Ed. 129(2016) 588-592.

[3] A. Han, P. Du, J. Energy Chem. 23(2014) 179-184.

[4] N. Jiang, B. You, M. Sheng, Y. Sun, Angew. Chem. Int. Ed. 54(2015) 6251-6254.

[5] L.-A. Stern, L. Feng, F. Song, X. Hu, Energy Environ. Sci. 8(2015) 2347-2351.

[6] B. You, Y. Sun, Adv. Energy Mater. 6(2016) 1502333.

[7] G.-F. Chen, T.Y. Ma, Z.-Q. Liu, N. Li, Y.-Z. Su, K. Davey, S.-Z. Qiao, Adv. Funct. Mater. 26(2016) 3314-3323.

[8] J. Li, D. Gao, J. Wang, S. Miao, G. Wang, X. Bao, J. Energy Chem. 24(2015) 608-613.

[9] T. Sun, L. Xu, Y. Yan, A.A. Zakhidov, R.H. Baughman, J. Chen, ACS Catal., 6(2016) 1446-1450.

[10] J.X. Feng, S.H. Ye, H. Xu, Y.X. Tong, G.R. Li, Adv. Mater. 28(2016) 4698-4703.

[11] X. Liu, M. Park, M.G. Kim, S. Gupta, G. Wu, J. Cho, Angew. Chem. Int. Ed. 54(2015) 9654-9658.

[12] C. Dai, X. Tian, Y. Nie, C. Tian, C. Yang, Z. Zhou, Y. Li, X. Gao, Chem. Eng. J. 321(2017) 105-112.

[13] Q. Liu, J. Shi, J. Hu, A.M. Asiri, Y. Luo, X. Sun, ACS Appl. Mater. Interfaces. 7(2015) 3877-3881.

[14] W. Ma, R. Ma, C. Wang, J. Liang, X. Liu, K. Zhou, T. Sasaki, ACS nano 9(2015) 1977-1984.

[15] J. Chang, Y. Xiao, M. Xiao, J. Ge, C. Liu, W. Xing, ACS Catal., 5(2015) 6874-6878.

[16] Y. Liang, Q. Liu, A.M. Asiri, X. Sun, Y. Luo, ACS Catal. 4(2014) 4065-4069.

[17] C. Ouyang, X. Wang, C. Wang, X. Zhang, J. Wu, Z. Ma, S. Dou, S. Wang, Electrochim. Acta 174(2015) 297-301.

[18] Y.P. Zhu, T.Y. Ma, M. Jaroniec, S.Z. Qiao, Angew. Chem. Int. Ed. 56(2016) 1324-1328.

[19] B. You, N. Jiang, M. Sheng, M.W. Bhushan, Y. Sun, ACS Catal 5(2015) 714-721.

[20] J. Ryu, N. Jung, J.H. Jang, H.-J. Kim, S.J. Yoo, ACS Catal 5(2015) 4066-4074.

[21] Y.P. Zhu, Y.P. Liu, T.Z. Ren, Z.Y. Yuan, Adv. Funct. Mater. 25(2015) 7337-7347.

[22] M. Ledendecker, S. Krick Calderon, C. Papp, H.P. Steinruck, M. Antonietti, M. Shalom, Angew. Chem. Int. Ed. 54(2015) 12361-12365.

[23] J. Jiang, C. Wang, J. Zhang, W. Wang, X. Zhou, B. Pan, K. Tang, J. Zuo, Q. Yang, J. Mater. Chem. A 3(2015) 499-503.

[24] D. Wang, X. Zhang, D. Zhang, Y. Shen, Z. Wu, Appl. Catal. A Gen. 511(2016) 11-15.

[25] Y.P. Zhu, X. Xu, H. Su, Y.P. Liu, T. Chen, Z.Y. Yuan, ACS Appl. Mater. Interfaces 7(2015) 28369-28376.

[26] J. Hao, W. Yang, Z. Huang, C. Zhang, Adv. Mater. Interfaces 3(2016) 1600236.

[27] C. Wang, J. Jiang, T. Ding, G. Chen, W. Xu, Q. Yang, Adv. Mater. Interfaces 3(2015) 1500454.

[28] J.M. McEnaney, J.C. Crompton, J.F. Callejas, E.J. Popczun, C.G. Read, N.S. Lewis, R.E. Schaak, Chem. Commun. 50(2014) 11026-11028.

[29] Y. Pan, Y. Liu, J. Zhao, K. Yang, J. Liang, D. Liu, W. Hu, D. Liu, Y. Liu, C. Liu, J. Mater. Chem. A 3(2015) 1656-1665.

[30] J. Chang, Q. Lv, G. Li, J. Ge, C. Liu, W. Xing, Appl. Catal. B-Environ. 204(2017) 486-496.

[31] X. Wang, W. Li, D. Xiong, D.Y. Petrovykh, L. Liu, Adv. Funct. Mater. 26(2016) 4067-4077.

[32] G. Zhang, B.Y. Xia, X. Wang, X.W. David Lou, Adv. Mater. 26(2014) 2408-2412.

[33] C. Tang, N. Cheng, Z. Pu, W. Xing, X. Sun, Angew. Chem. Int. Ed. 54(2015) 9351-9355.

[34] C. Tang, Z. Pu, Q. Liu, A.M. Asiri, X. Sun, Electrochim. Acta 153(2015) 508-514.

[35] N. Jiang, B. You, M. Sheng, Y. Sun, ChemCatChem 8(2016) 106-112.

[36] Y. Wu, G.-D. Li, Y. Liu, L. Yang, X. Lian, T. Asefa, X. Zou, Adv. Funct. Mater. 26(2016) 4839-4847.

[37] J. Zhang, T. Wang, D. Pohl, B. Rellinghaus, R. Dong, S. Liu, X. Zhuang, X. Feng, Angew. Chem. Int. Ed. 55(2016) 6702-6707.

[38] W. Zhu, X. Yue, W. Zhang, S. Yu, Y. Zhang, J. Wang, J. Wang, Chem. Commun. 52(2016) 1486-1489.

[39] T.Y. Ma, S. Dai, M. Jaroniec, S.Z. Qiao, J. Am. Chem. Soc. 136(2014) 13925-13931.

[40] B. You, N. Jiang, M. Sheng, S. Gul, J. Yano, Y. Sun, Chem. Mater. 27(2015) 7636-7642.

[41] G. Huang, H. Liu, S. Wang, X. Yang, B.H. Liu, H. Chen, M. Xu, J. Mater. Chem. A 3(2015) 24128-24138.

[42] J. Li, X. Zhou, Z. Xia, Z. Zhang, J. Li, Y. Ma, Y. Qu, J. Mater. Chem. A 3(2015) 13066-13071.

[43] J. Yin, P. Zhou, L. An, L. Huang, C. Shao, J. Wang, H. Liu, P. Xi, Nanoscale 8(2016) 1390-1400.

[44] Y. Nie, L. Li, Z. Wei, Chem. Soc. Rev. 44(2015) 2168-2201.

Integrated Ni₂P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation

Integrated Ni₂P nanosheet arrays on three-dimensional Ni foam for highly efficient water reduction and oxidation

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	Yuefeng Zhang, Wenchao Zhang, Yuezhan Feng, Jianmin Ma. Promoted CO₂ electroreduction over indium-doped SnP₃: A computational study[J]. 能源化学(英文版), 2020, 48(9): 1-6.
[2]	Sasan Ghashghaie, Samson Ho-Sum Cheng, Jie Fang, Hafiz Khurram Shahzad, Robin Lok-Wang Ma, chi-Yuen Chung. Electrophoretically deposited binder-free 3-D carbon/sulfur nanocomposite cathode for high-performance Li-S batteries[J]. 能源化学(英文版), 2020, 48(9): 92-101.
[3]	Bo Xu, Xiaodong Yang, Qiang Fang, Linbing Du, Yan Fu, Yiqiang Sun, Qisheng Liu, Qingquan Lin, cuncheng Li. Anion-cation dual doping: An effective electronic modulation strategy of Ni₂P for high-performance oxygen evolution[J]. 能源化学(英文版), 2020, 48(9): 116-121.
[4]	Jing-Yi Xie, Zi-Zhang Liu, Jia Li, Lei Feng, Min Yang, Yu Ma, da-Peng Liu, Lei Wang, Yong-Ming Chai, bin Dong. Fe-doped CoP core-shell structure with open cages as efficient electrocatalyst for oxygen evolution[J]. 能源化学(英文版), 2020, 48(9): 328-333.
[5]	Jing-Qi Chi, Min Yang, Yong-Ming Chai, Zhi Yang, Lei Wang, bin Dong. Design and modulation principles of molybdenum carbide-based materials for green hydrogen evolution[J]. 能源化学(英文版), 2020, 48(9): 398-423.
[6]	Rong Jiang, Xin Chen, Jinxia Deng, Tianyu Wang, Kang Wang, Yanli Chen, Jianzhuang Jiang. In-situ growth of ZnS/FeS heterojunctions on biomass-derived porous carbon for efficient oxygen reduction reaction[J]. 能源化学(英文版), 2020, 47(8): 79-85.
[7]	Jae Hyeon Nam, Myeong Je Jang, Hye Yeon Jang, Woojin Park, Xiaolei Wang, Sung Mook Choi,byungjin Cho. Room-temperature sputtered electrocatalyst WSe₂ nanomaterials for hydrogen evolution reaction[J]. 能源化学(英文版), 2020, 47(8): 107-111.
[8]	Mengfei Qiao, Ying Wang, Thomas Wågberg, Xamxikamar Mamat, Xun Hu, Guoan Zou, Guangzhi Hu. Ni-Co bimetallic coordination effect for long lifetime rechargeable Zn-air battery[J]. 能源化学(英文版), 2020, 47(8): 146-154.
[9]	Yuxiao Ding, Qingqing Gu, Alexander Klyushin, Xing Huang, Sakeb H.Choudhury, Ioannis Spanos,feihong Song, Rik Mom, Pascal Düngen, Anna K.Mechler, Robert Schlögl, Saskia Heumann. Dynamic carbon surface chemistry: Revealing the role of carbon in electrolytic water oxidation[J]. 能源化学(英文版), 2020, 47(8): 155-159.
[10]	Meng Zha,chengang Pei, Quan Wang, Guangzhi Hu, Ligang Feng. Electrochemical oxygen evolution reaction efficiently boosted by selective fluoridation of FeNi₃ alloy/oxide hybrid[J]. 能源化学(英文版), 2020, 47(8): 166-171.
[11]	Hui-Ying Sun, Guang-Rui Xu,fu-Min Li, Qing-Ling Hong, Pu-Jun Jin, Pei Chen, Yu Chen. Hydrogen generation from ammonia electrolysis on bifunctional platinum nanocubes electrocatalysts[J]. 能源化学(英文版), 2020, 47(8): 234-240.
[12]	Danyang He, Liyun Cao, Jianfeng Huang, Koji Kajiyoshi, Jianpeng Wu,changcong Wang, Qianqian Liu,dan Yang, Liangliang Feng. In-situ optimizing the valence configuration of vanadium sites in NiV-LDH nanosheet arrays for enhanced hydrogen evolution reaction[J]. 能源化学(英文版), 2020, 47(8): 263-271.
[13]	Shijie Zhang, Peng Zhang, Ruohan Hou,bin Li, Yongshang Zhang, Kangli Liu, Xilai Zhang, Guosheng Shao. In situ sulfur-doped graphene nanofiber network as efficient metal-free electrocatalyst for polysulfides redox reactions in lithium-sulfur batteries[J]. 能源化学(英文版), 2020, 47(8): 281-290.
[14]	Ruiqin Gao, Qi Zhang, Hui Chen, Xuefeng Chu, Guo-Dong Li, Xiaoxin Zou. Efficient acidic oxygen evolution reaction electrocatalyzed by iridium-based 12L-perovskites comprising trinuclear face-shared IrO₆ octahedral strings[J]. 能源化学(英文版), 2020, 47(8): 291-298.
[15]	Puxuan Yan, Meilin Huang,benzhi Wang, Zixia Wan, Mancai Qian, Hu Yan, Tayirjan Taylor Isimjan, Jianniao Tian, Xiulin Yang. Oxygen defect-rich double-layer hierarchical porous Co₃O₄ arrays as high-efficient oxygen evolution catalyst for overall water splitting[J]. 能源化学(英文版), 2020, 47(8): 299-306.