能源化学(英文版)

能源化学(英文) ›› 2018, Vol. 27 ›› Issue (6): 1536-1554.DOI: 10.1016/j.jechem.2018.01.009

• Review • 上一篇    下一篇

The application of nanostructured transition metal sulfides as anodes for lithium ion batteries

Jinbao Zhao, Yiyong Zhang, Yunhui Wang, He Li, Yueying Peng   

  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, State-Province Joint Engineering Laboratory of Power Source Technology for New Energy Vehicle, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
  • 收稿日期:2017-12-25 修回日期:2018-01-10 出版日期:2018-11-15 发布日期:2018-10-12
  • 通讯作者: Jinbao Zhao
  • 作者简介:Jinbao Zhao has been engaged in the development and commercialization of chemical power (especially lithium ion batteries) and functional polymer materials, especially in the Japanese Hitachi Group for more than 10 years. He has worked in College of Chemistry and Chemical Engineering, Xiamen University (focusing on lithiumbased batteries) since 2011;Yiyong Zhang is now a Ph.D. candidate supervised by Prof. Jinbao Zhao in the Department of Chemical and Biological Engineering at the Xiamen University.
  • 基金资助:

    We gratefully acknowledge the financial support of the National Natural Science Foundation of China (21273185 and 21621091) and the National Found for Fostering Talents of Basic Science (J1310024).

The application of nanostructured transition metal sulfides as anodes for lithium ion batteries

Jinbao Zhao, Yiyong Zhang, Yunhui Wang, He Li, Yueying Peng   

  1. State Key Laboratory of Physical Chemistry of Solid Surfaces, State-Province Joint Engineering Laboratory of Power Source Technology for New Energy Vehicle, Collaborative Innovation Center of Chemistry for Energy Materials, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China
  • Received:2017-12-25 Revised:2018-01-10 Online:2018-11-15 Published:2018-10-12
  • Contact: Jinbao Zhao
  • About author:Jinbao Zhao has been engaged in the development and commercialization of chemical power (especially lithium ion batteries) and functional polymer materials, especially in the Japanese Hitachi Group for more than 10 years. He has worked in College of Chemistry and Chemical Engineering, Xiamen University (focusing on lithiumbased batteries) since 2011;Yiyong Zhang is now a Ph.D. candidate supervised by Prof. Jinbao Zhao in the Department of Chemical and Biological Engineering at the Xiamen University.
  • Supported by:

    We gratefully acknowledge the financial support of the National Natural Science Foundation of China (21273185 and 21621091) and the National Found for Fostering Talents of Basic Science (J1310024).

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摘要： With wide application of electric vehicles and large-scale in energy storage systems, the requirement of secondary batteries with higher power density and better safety gets urgent. Owing to the merits of high theoretical capacity, relatively low cost and suitable discharge voltage, much attention has been paid to the transition metal sulfides. Recently, a large amount of research papers have reported about the application of transition metal sulfides in lithium ion batteries. However, the practical application of transition metal sulfides is still impeded by their fast capacity fading and poor rate performance. More well-focused researches should be operated towards the commercialization of transition metal sulfides in lithium ion batteries. In this review, recent development of using transition metal sulfides such as copper sulfides, molybdenum sulfides, cobalt sulfides, and iron sulfides as electrode materials for lithium ion batteries is presented. In addition, the electrochemical reaction mechanisms and synthetic strategy of transition metal sulfides are briefly summarized. The critical issues, challenges, and perspectives providing a further understanding of the associated electrochemical processes are also discussed.

关键词: Transition metal sulfides, Lithium ion battery, Anode

Abstract: With wide application of electric vehicles and large-scale in energy storage systems, the requirement of secondary batteries with higher power density and better safety gets urgent. Owing to the merits of high theoretical capacity, relatively low cost and suitable discharge voltage, much attention has been paid to the transition metal sulfides. Recently, a large amount of research papers have reported about the application of transition metal sulfides in lithium ion batteries. However, the practical application of transition metal sulfides is still impeded by their fast capacity fading and poor rate performance. More well-focused researches should be operated towards the commercialization of transition metal sulfides in lithium ion batteries. In this review, recent development of using transition metal sulfides such as copper sulfides, molybdenum sulfides, cobalt sulfides, and iron sulfides as electrode materials for lithium ion batteries is presented. In addition, the electrochemical reaction mechanisms and synthetic strategy of transition metal sulfides are briefly summarized. The critical issues, challenges, and perspectives providing a further understanding of the associated electrochemical processes are also discussed.

Key words: Transition metal sulfides, Lithium ion battery, Anode