能源化学(英文版)

能源化学(英文) ›› 2018, Vol. 27 ›› Issue (6): 1584-1596.DOI: 10.1016/j.jechem.2018.03.004

• Review • 上一篇    下一篇

Advanced Na metal anodes

Chenglong Zhaoa,b, Yaxiang Lua,b, Jinming Yuea,b, Du Pana,b, Yuruo Qia,b, Yong-Sheng Hua,b, Liquan Chena,b   

  1. a Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
    b School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China
  • 收稿日期:2018-01-30 修回日期:2018-03-12 出版日期:2018-11-15 发布日期:2018-10-12
  • 通讯作者: Yaxiang Lu, Yong-Sheng Hu
  • 作者简介:Chenglong Zhao received his B.S and B.Admin. degrees from China University of Geosciences in Beijing, in 2015;Yaxiang Lu received her Ph.D. degree at University of Birmingham (UK), and then she moved to University of Surrey (UK) to work as the research fellow. After that she is awarded the International Young Scientist Fellowship by the Institute of Physics (IOP), Chinese Academy of Sciences (CAS) following Prof. Yong-sheng Hu;Jinming Yue received her B.S. and B.Admin. degrees from Zhejiang Sci-Tech University in Zhejiang, in 2016;Du Pan received his B.S degree in 2014 from Xinyang Normal University;Yuruo Qi received her B.S degree in 2013 from SiChuan University. She is now a Ph.D. candidate following Prof. Yong-Sheng Hu, in Institute of Physics, Chinese Academy of Sciences (IOP-CAS) on novel energy storage and conversion materials.
  • 基金资助:

    This work was supported by the National Key Technologies R&D Program, China (2016YFB0901500), the National Natural Science Foundation of China (51672275, 51421002).

Advanced Na metal anodes

Chenglong Zhaoa,b, Yaxiang Lua,b, Jinming Yuea,b, Du Pana,b, Yuruo Qia,b, Yong-Sheng Hua,b, Liquan Chena,b   

  1. a Key Laboratory for Renewable Energy, Beijing Key Laboratory for New Energy Materials and Devices, Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China;
    b School of Physical Sciences, University of Chinese Academy of Sciences, Beijing 100190, China
  • Received:2018-01-30 Revised:2018-03-12 Online:2018-11-15 Published:2018-10-12
  • Contact: Yaxiang Lu, Yong-Sheng Hu
  • About author:Chenglong Zhao received his B.S and B.Admin. degrees from China University of Geosciences in Beijing, in 2015;Yaxiang Lu received her Ph.D. degree at University of Birmingham (UK), and then she moved to University of Surrey (UK) to work as the research fellow. After that she is awarded the International Young Scientist Fellowship by the Institute of Physics (IOP), Chinese Academy of Sciences (CAS) following Prof. Yong-sheng Hu;Jinming Yue received her B.S. and B.Admin. degrees from Zhejiang Sci-Tech University in Zhejiang, in 2016;Du Pan received his B.S degree in 2014 from Xinyang Normal University;Yuruo Qi received her B.S degree in 2013 from SiChuan University. She is now a Ph.D. candidate following Prof. Yong-Sheng Hu, in Institute of Physics, Chinese Academy of Sciences (IOP-CAS) on novel energy storage and conversion materials.
  • Supported by:

    This work was supported by the National Key Technologies R&D Program, China (2016YFB0901500), the National Natural Science Foundation of China (51672275, 51421002).

PDF

7

摘要： Na metal anode, benefiting from its high theoretical capacity and lowest electrochemical potential, is one of the most favorable candidates for future Na-based batteries with high energy density. Dendrite growth, volume change and high reactivity are the formidable challenges in terms of good cycling performance and high Coulombic efficiency as well as an expected safety guarantee of Na metal anode for the practical application. Solid electrolyte interphase (SEI) layer as an indispensable component of a battery, its formation and stability play the critical role in the feasibility of Na metal anode. In this review, we first discuss the current consideration and challenges of Na metal anode, and then summarize several strategies to suppress dendrite growth and improve electrochemical performance, including interface engineering, electrolyte composition, electrode construction, and so on. Finally, the conclusion and future perspective of potential development on Na metal anode are proposed.

关键词: Na metal anode, Solid electrolyte interphase, Electrolyte, Dendrite, Na-metal batteries

Abstract: Na metal anode, benefiting from its high theoretical capacity and lowest electrochemical potential, is one of the most favorable candidates for future Na-based batteries with high energy density. Dendrite growth, volume change and high reactivity are the formidable challenges in terms of good cycling performance and high Coulombic efficiency as well as an expected safety guarantee of Na metal anode for the practical application. Solid electrolyte interphase (SEI) layer as an indispensable component of a battery, its formation and stability play the critical role in the feasibility of Na metal anode. In this review, we first discuss the current consideration and challenges of Na metal anode, and then summarize several strategies to suppress dendrite growth and improve electrochemical performance, including interface engineering, electrolyte composition, electrode construction, and so on. Finally, the conclusion and future perspective of potential development on Na metal anode are proposed.

Key words: Na metal anode, Solid electrolyte interphase, Electrolyte, Dendrite, Na-metal batteries