能源化学(英文版)

能源化学(英文) ›› 2018, Vol. 27 ›› Issue (6): 1597-1617.DOI: 10.1016/j.jechem.2018.05.001

• Review • 上一篇    下一篇

Progress and prospect for NASICON-type Na3V2(PO4)3 for electrochemical energy storage

Qiong Zhenga, Hongming Yia,b, Xianfeng Lia,c, Huamin Zhanga,c   

  1. a Division of Energy Storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
    b University of Chinese Academy of Sciences, Beijing 100039, China;
    c Collaborative Innovation Center of Chemistry for Energy Materials(iChEM), Dalian 116023, Liaoning, China
  • 收稿日期:2018-02-19 修回日期:2018-05-03 出版日期:2018-11-15 发布日期:2018-10-12
  • 通讯作者: Qiong Zheng, Huamin Zhang
  • 作者简介:Qiong Zheng received her PhD. from Dalian University of Technology in 2015. Then she worked as a postdotor with Prof. Huamin Zhang in Dalian Institute of Chemical Physics, CAS for two years;Hongming Yi got his Bachelor degree from Lanzhou University in 2015. He is presently a PhD student under the supervision of Prof. Huamin Zhang;Xianfeng Li was born in 1979 in China. He received his PhD in polymer chemistry and physics from Jilin University in 2006. After 3 years' postdoc with Prof. Vankelecom from K. U. Leuven, he was appointed as an associate professor in Dalian Institute of Chemical Physics, CAS;Huamin Zhang currently serves as a tenure-track full professor at Dalian Institute of Chemical Physics, CAS; He is also CTO of Dalian Rongke Power Co., Ltd, director of the state key lab of flow battery for energy storage and National Technical Committee on flow battery standardization.
  • 基金资助:

    The authors acknowledge financial support from the National Natural Science Foundation of China (No. 21501171, 51403209, 21406221, 51177156/E0712).

Progress and prospect for NASICON-type Na3V2(PO4)3 for electrochemical energy storage

Qiong Zhenga, Hongming Yia,b, Xianfeng Lia,c, Huamin Zhanga,c   

  1. a Division of Energy Storage, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, Liaoning, China;
    b University of Chinese Academy of Sciences, Beijing 100039, China;
    c Collaborative Innovation Center of Chemistry for Energy Materials(iChEM), Dalian 116023, Liaoning, China
  • Received:2018-02-19 Revised:2018-05-03 Online:2018-11-15 Published:2018-10-12
  • Contact: Qiong Zheng, Huamin Zhang
  • About author:Qiong Zheng received her PhD. from Dalian University of Technology in 2015. Then she worked as a postdotor with Prof. Huamin Zhang in Dalian Institute of Chemical Physics, CAS for two years;Hongming Yi got his Bachelor degree from Lanzhou University in 2015. He is presently a PhD student under the supervision of Prof. Huamin Zhang;Xianfeng Li was born in 1979 in China. He received his PhD in polymer chemistry and physics from Jilin University in 2006. After 3 years' postdoc with Prof. Vankelecom from K. U. Leuven, he was appointed as an associate professor in Dalian Institute of Chemical Physics, CAS;Huamin Zhang currently serves as a tenure-track full professor at Dalian Institute of Chemical Physics, CAS; He is also CTO of Dalian Rongke Power Co., Ltd, director of the state key lab of flow battery for energy storage and National Technical Committee on flow battery standardization.
  • Supported by:

    The authors acknowledge financial support from the National Natural Science Foundation of China (No. 21501171, 51403209, 21406221, 51177156/E0712).

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摘要： Sodium-ion batteries (SIBs) have attracted increasing attention in the past decades, because of high overall abundance of precursors, their even geographical distribution, and low cost. Na3V2(PO4)3 (NVP), a typical sodium super ion conductor (NASICON)-based electrode material, exhibits pronounced structural stability, exceptionally high ion conductivity, rendering it a most promising electrode for sodium storage. However, the comparatively low electronic conductivity makes the theoretical capacity of NVP cannot be fully accessible even at comparatively low rates, presenting a major drawback for further practical applications, especially when high rate capability is especially important. Thus, many endeavors have been conformed to increase the surface and intrinsic electrical conductivity of NVP by coating the active materials with a conductive carbon layer, downsizing the NVP particles, combining the NVP particle with various carbon materials and ion doping strategy. In this review, to get a better understanding on the sodium storage in NVP, we firstly present 4 distinct crystal structures in the temperature range of -30℃~225℃ namely α-NVP, β-NVP, β'-NVP and γ-NVP. Moreover, we give an overview of recent approaches to enhance the surface electrical conductivity and intrinsic electrical conductivity of NVP. Finally, some potential applications of NVP such as in all-climate environment and PHEV, EV fields have been prospected.

关键词: Sodium ion batteries, Na3V2(PO4)3, Crystal structure, Electrical conductivity, Energy storage

Abstract: Sodium-ion batteries (SIBs) have attracted increasing attention in the past decades, because of high overall abundance of precursors, their even geographical distribution, and low cost. Na3V2(PO4)3 (NVP), a typical sodium super ion conductor (NASICON)-based electrode material, exhibits pronounced structural stability, exceptionally high ion conductivity, rendering it a most promising electrode for sodium storage. However, the comparatively low electronic conductivity makes the theoretical capacity of NVP cannot be fully accessible even at comparatively low rates, presenting a major drawback for further practical applications, especially when high rate capability is especially important. Thus, many endeavors have been conformed to increase the surface and intrinsic electrical conductivity of NVP by coating the active materials with a conductive carbon layer, downsizing the NVP particles, combining the NVP particle with various carbon materials and ion doping strategy. In this review, to get a better understanding on the sodium storage in NVP, we firstly present 4 distinct crystal structures in the temperature range of -30℃~225℃ namely α-NVP, β-NVP, β'-NVP and γ-NVP. Moreover, we give an overview of recent approaches to enhance the surface electrical conductivity and intrinsic electrical conductivity of NVP. Finally, some potential applications of NVP such as in all-climate environment and PHEV, EV fields have been prospected.

Key words: Sodium ion batteries, Na3V2(PO4)3, Crystal structure, Electrical conductivity, Energy storage