能源化学(英文版)

能源化学(英文) ›› 2019, Vol. 28 ›› Issue (7): 80-87.DOI: 10.1016/j.jechem.2018.09.022

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Highly efficient extraction of lithium from salt lake brine by LiAl-layered double hydroxides as lithium-ion-selective capturing material

Ying Sun, Xiaoyu Guo, Shaofang Hu, Xu Xiang   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • 收稿日期:2018-07-28 修回日期:2018-09-11 出版日期:2019-07-15 发布日期:2019-07-15
  • 通讯作者: Xu Xiang
  • 基金资助:
    This work was supported by the National Natural Science Foundation of China (Grant U1507202, U1707603), the Innovative Research Groups of National Natural Science Foundation of China (Grant 21521005) and the Key R&D Program of Qinghai Province (Grant 2017-GX-144).

Highly efficient extraction of lithium from salt lake brine by LiAl-layered double hydroxides as lithium-ion-selective capturing material

Ying Sun, Xiaoyu Guo, Shaofang Hu, Xu Xiang   

  1. State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2018-07-28 Revised:2018-09-11 Online:2019-07-15 Published:2019-07-15
  • Contact: Xu Xiang
  • Supported by:
    This work was supported by the National Natural Science Foundation of China (Grant U1507202, U1707603), the Innovative Research Groups of National Natural Science Foundation of China (Grant 21521005) and the Key R&D Program of Qinghai Province (Grant 2017-GX-144).

摘要： The extraction of lithium from salt lake brine in the Chinese Qaidam Basin is challenging due to its high Mg/Li and Na/Li ratios. Herein, we utilized a reaction-coupled separation technology to separate sodium and lithium ions from a high Na/Li ratio brine (Na/Li=48.7, w/w) and extracted lithium with LiAl-layered double hydroxides (LiAl-LDHs). The LiAl-LDHs act as lithium-ion-selective capturing materials from multication brines. That is, the lithium ions selectively enter the solid phase to form LiAl-LDHs, and the sodium ions are still retained in the liquid phase. This is because the lithium ions can be incorporated into the structural vacancies of LiAl-LDHs, whereas the sodium ions cannot. The effects of reaction conditions on lithium loss and separation efficiency were investigated at both the nucleation and the crystallization stage, e.g., the nucleation rotating speed, the Li/Al molar ratio, the crystallization temperature and time, and co-existing cations. The lithium loss is as low as 3.93% under optimal separation conditions. The sodium ions remained in the solution. Consequently, an excellent Na/Li separation efficiency was achieved by this reaction-coupled separation technology. These findings confirm that LiAl-LDHs play a critical function in selectively capturing lithium ions from brines with a high Na/Li ratio, which is useful for the extraction of lithium ions from the abundant salt lake brine resources in China.

关键词: LiAl-LDHs, Lithium extraction, Energy metal, Salt lake brine, Reaction-coupled separation technology

Abstract: The extraction of lithium from salt lake brine in the Chinese Qaidam Basin is challenging due to its high Mg/Li and Na/Li ratios. Herein, we utilized a reaction-coupled separation technology to separate sodium and lithium ions from a high Na/Li ratio brine (Na/Li=48.7, w/w) and extracted lithium with LiAl-layered double hydroxides (LiAl-LDHs). The LiAl-LDHs act as lithium-ion-selective capturing materials from multication brines. That is, the lithium ions selectively enter the solid phase to form LiAl-LDHs, and the sodium ions are still retained in the liquid phase. This is because the lithium ions can be incorporated into the structural vacancies of LiAl-LDHs, whereas the sodium ions cannot. The effects of reaction conditions on lithium loss and separation efficiency were investigated at both the nucleation and the crystallization stage, e.g., the nucleation rotating speed, the Li/Al molar ratio, the crystallization temperature and time, and co-existing cations. The lithium loss is as low as 3.93% under optimal separation conditions. The sodium ions remained in the solution. Consequently, an excellent Na/Li separation efficiency was achieved by this reaction-coupled separation technology. These findings confirm that LiAl-LDHs play a critical function in selectively capturing lithium ions from brines with a high Na/Li ratio, which is useful for the extraction of lithium ions from the abundant salt lake brine resources in China.

Key words: LiAl-LDHs, Lithium extraction, Energy metal, Salt lake brine, Reaction-coupled separation technology