能源化学(英文版)

能源化学(英文) ›› 2019, Vol. 28 ›› Issue (7): 220-226.DOI: 10.1016/j.jechem.2018.10.006

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N/S co-doped 3D carbon framework prepared by a facile morphology-controlled solid-state pyrolysis method for oxygen reduction reaction in both acidic and alkaline media

Juan Nonga, Min Zhua, Kun Heb, Aosheng Zhua, Pu Xiea, Minzhi Ronga, Mingqiu Zhanga   

  1. a Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, DSAPM Lab, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, Guangdong, China;
    b China Building Materials Academy, Beijing 100024, China
  • 收稿日期:2018-08-11 修回日期:2018-10-11 出版日期:2019-07-15 发布日期:2019-07-15
  • 通讯作者: Pu Xie
  • 基金资助:
    The authors are grateful to the financial support by the National Natural Science Foundation of China (Grant:51333008) and Young Teacher Training Program of Sun Yat-sen University (Grant:17lgpy86).

N/S co-doped 3D carbon framework prepared by a facile morphology-controlled solid-state pyrolysis method for oxygen reduction reaction in both acidic and alkaline media

Juan Nonga, Min Zhua, Kun Heb, Aosheng Zhua, Pu Xiea, Minzhi Ronga, Mingqiu Zhanga   

  1. a Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education, DSAPM Lab, School of Chemistry, Sun Yat-sen University, Guangzhou 510275, Guangdong, China;
    b China Building Materials Academy, Beijing 100024, China
  • Received:2018-08-11 Revised:2018-10-11 Online:2019-07-15 Published:2019-07-15
  • Contact: Pu Xie
  • Supported by:
    The authors are grateful to the financial support by the National Natural Science Foundation of China (Grant:51333008) and Young Teacher Training Program of Sun Yat-sen University (Grant:17lgpy86).

摘要： Developing high-performance non-precious metal electrocatalysts for oxygen reduction reaction (ORR) is crucial for the commercialization of fuel cells and metal-air batteries. However, doped carbon-based materials only show good ORR activity in alkaline medium, and become less effective in acidic environment. We believe that an appropriate combination of both ionic and electronic transport path, and well dopant distribution of doped carbon-based materials would help to realize high ORR performance under both acidic and alkaline conditions. Accordingly, a nitrogen and sulfur co-doped carbon framework with hierarchical through-hole structure is fabricated by morphology-controlled solid-state pyrolysis of poly(aniline-co-2-aminothiophenol) foam. The uniform high concentrations of nitrogen and sulfur, high intrinsic conductivity, and integrated three dimensional ionic and electronic transfer passageways of the 3D porous structure lead to synergistic effects in catalyzing ORR. As a result, the limiting current density of the carbonized poly(aniline-co-2-aminothiophenol) foam is equivalent to commercial Pt/C in acidic environment, and twice the latter in alkaline medium.

关键词: 3D N/S-doped carbon frameworks, Oxygen reduction reaction (ORR), Morphology-retaining pyrolysis, Acidic medium

Abstract: Developing high-performance non-precious metal electrocatalysts for oxygen reduction reaction (ORR) is crucial for the commercialization of fuel cells and metal-air batteries. However, doped carbon-based materials only show good ORR activity in alkaline medium, and become less effective in acidic environment. We believe that an appropriate combination of both ionic and electronic transport path, and well dopant distribution of doped carbon-based materials would help to realize high ORR performance under both acidic and alkaline conditions. Accordingly, a nitrogen and sulfur co-doped carbon framework with hierarchical through-hole structure is fabricated by morphology-controlled solid-state pyrolysis of poly(aniline-co-2-aminothiophenol) foam. The uniform high concentrations of nitrogen and sulfur, high intrinsic conductivity, and integrated three dimensional ionic and electronic transfer passageways of the 3D porous structure lead to synergistic effects in catalyzing ORR. As a result, the limiting current density of the carbonized poly(aniline-co-2-aminothiophenol) foam is equivalent to commercial Pt/C in acidic environment, and twice the latter in alkaline medium.

Key words: 3D N/S-doped carbon frameworks, Oxygen reduction reaction (ORR), Morphology-retaining pyrolysis, Acidic medium