Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide

doi:10.1016/j.jechem.2019.01.001

能源化学(英文版) ›› 2019, Vol. 38 ›› Issue (11): 34-40.DOI: 10.1016/j.jechem.2019.01.001

Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide

Changqi Sun^a,c, Xiaosong Guo^b, Jingyan Zhang^c, Genliang Han^a, Daqiang Gao^c, Xiaoping Gao^a

a Key Laboratory of Sensor and Sensing Technology, Gansu Academy of Sciences, Lanzhou 730000, Gansu, China;
b College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong, China;
c Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, Gansu, China

收稿日期:2018-10-29 修回日期:2019-01-07 出版日期:2019-11-15 发布日期:2020-12-18
通讯作者: Daqiang Gao, gaodq@lzu.edu.cn; Xiaoping Gao, gao_xp02@163.com
基金资助:
This work is supported by the National Natural Science Foundation of China (Grant nos. 11474137), the Fundamental Research Funds for the Central Universities (Grant nos. LZUMMM2018017, lzujbky-2018-121), Key Research and Development Plan of Gansu Province (No. 18YF1GA088) and Scientific research project of colleges and universities in gansu province (No. 2018A-205).

Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide

Changqi Sun^a,c, Xiaosong Guo^b, Jingyan Zhang^c, Genliang Han^a, Daqiang Gao^c, Xiaoping Gao^a

a Key Laboratory of Sensor and Sensing Technology, Gansu Academy of Sciences, Lanzhou 730000, Gansu, China;
b College of Materials Science and Engineering, Qingdao University of Science and Technology, Qingdao 266061, Shandong, China;
c Key Laboratory for Magnetism and Magnetic Materials of MOE, Key Laboratory of Special Function Materials and Structure Design of MOE, Lanzhou University, Lanzhou 730000, Gansu, China

Received:2018-10-29 Revised:2019-01-07 Online:2019-11-15 Published:2020-12-18
Contact: Daqiang Gao, gaodq@lzu.edu.cn; Xiaoping Gao, gao_xp02@163.com
Supported by:
This work is supported by the National Natural Science Foundation of China (Grant nos. 11474137), the Fundamental Research Funds for the Central Universities (Grant nos. LZUMMM2018017, lzujbky-2018-121), Key Research and Development Plan of Gansu Province (No. 18YF1GA088) and Scientific research project of colleges and universities in gansu province (No. 2018A-205).

摘要/Abstract

摘要： A Zn-air battery is a potential next-generation energy storage device owing to its extremely high theoretical energy density. Currently, it is important to explore non-precious metal electrocatalysts with high electroactivity and stability in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) for the development of Zn-air batteries. In this work, porous (Ni,Co)Se₂ nanosheets were synthesized by selenizing NiCo₂O₄ nanosheets. By regulating the conductivity and morphology of the sample, the prepared porous (Ni,Co)Se₂ nanosheets show enhanced electrocatalytic activity for OER and ORR compared to NiCo₂O₄ nanosheets. The aqueous Zn-air battery using porous (Ni,Co)Se₂ nanosheets as the air cathode exhibits superior charge and discharge performance (1.98 V for charging and 1.17 V for discharging), high specific capacity (770 mAh/g), and excellent cycle stability (140 h). These results indicate that the porous (Ni,Co)Se₂ nanosheets are suitable as a bifunctional electrocatalyst for future Zn-air batteries.

关键词: Electrocatalyst, Zn-air batteries, Oxygen evolution reaction, Oxygen reduction reaction

Abstract: A Zn-air battery is a potential next-generation energy storage device owing to its extremely high theoretical energy density. Currently, it is important to explore non-precious metal electrocatalysts with high electroactivity and stability in the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) for the development of Zn-air batteries. In this work, porous (Ni,Co)Se₂ nanosheets were synthesized by selenizing NiCo₂O₄ nanosheets. By regulating the conductivity and morphology of the sample, the prepared porous (Ni,Co)Se₂ nanosheets show enhanced electrocatalytic activity for OER and ORR compared to NiCo₂O₄ nanosheets. The aqueous Zn-air battery using porous (Ni,Co)Se₂ nanosheets as the air cathode exhibits superior charge and discharge performance (1.98 V for charging and 1.17 V for discharging), high specific capacity (770 mAh/g), and excellent cycle stability (140 h). These results indicate that the porous (Ni,Co)Se₂ nanosheets are suitable as a bifunctional electrocatalyst for future Zn-air batteries.

Key words: Electrocatalyst, Zn-air batteries, Oxygen evolution reaction, Oxygen reduction reaction

Changqi Sun, Xiaosong Guo, Jingyan Zhang, Genliang Han, Daqiang Gao, Xiaoping Gao. Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide[J]. 能源化学(英文版), 2019, 38(11): 34-40.

Changqi Sun, Xiaosong Guo, Jingyan Zhang, Genliang Han, Daqiang Gao, Xiaoping Gao. Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide[J]. Journal of Energy Chemistry, 2019, 38(11): 34-40.

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Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide

Rechargeable Zn-air batteries initiated by nickel-cobalt bimetallic selenide

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