Fe3C-N-doped carbon modified separator for high performance lithium-sulfur batteries

能源化学(英文版) ›› 2019, Vol. 39 ›› Issue (12): 101-108.

Fe₃C-N-doped carbon modified separator for high performance lithium-sulfur batteries

Hongyu Pan^a,b, Zhong Tan^a,b, Haihui Zhou^a,b, Lanlan Jiang^a,b, Zhongyuan Huang^a,b, Qiaoxia Feng^a,b, Qiang Zhou^a,b, Shuai Ma^a,b, Yafei Kuang^a,b

a State Key Laboratory for Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, Hunan, China;
b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China

收稿日期:2018-11-13 修回日期:2019-01-18 出版日期:2019-12-15 发布日期:2020-12-18
通讯作者: Haihui Zhou, haihuizh@163.com; Zhongyuan Huang, zhongyuan.222@163.com; Yafei Kuang, yafeik@163.com
基金资助:
This work was supported by the National Natural Science Foundation of China (Grant no. 51672075, 21271069, 51772092, 51704106) and Science and Technology Program of Hunan Province (Grant no. 2015JC3049).

Fe₃C-N-doped carbon modified separator for high performance lithium-sulfur batteries

Hongyu Pan^a,b, Zhong Tan^a,b, Haihui Zhou^a,b, Lanlan Jiang^a,b, Zhongyuan Huang^a,b, Qiaoxia Feng^a,b, Qiang Zhou^a,b, Shuai Ma^a,b, Yafei Kuang^a,b

a State Key Laboratory for Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, Hunan, China;
b College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, Hunan, China

Received:2018-11-13 Revised:2019-01-18 Online:2019-12-15 Published:2020-12-18
Contact: Haihui Zhou, haihuizh@163.com; Zhongyuan Huang, zhongyuan.222@163.com; Yafei Kuang, yafeik@163.com
Supported by:
This work was supported by the National Natural Science Foundation of China (Grant no. 51672075, 21271069, 51772092, 51704106) and Science and Technology Program of Hunan Province (Grant no. 2015JC3049).

摘要/Abstract

摘要： A new Fe₃C-N-doped reduced graphene oxide (Fe₃C-N-rGO) prepared by a facile method is used as a separator for high performance lithium-sulfur (Li-S) batteries. The Fe₃C-N-rGO is coated on the surface of commercial polypropylene separator (Celgard 2400) close to the sulfur cathode. The special nanotubes are in-situ catalyzed by Fe₃C nanoparticles. They could entrap lithium polysulfides (LiPSs) to restrain the shuttle effect and reduce the loss of active material. The battery with the modified separator and sulfur cathode shows an excellent cycle performance. It has a high rate performance, 580.5 mAh/g at the high current rate of 4 C relative to 1075 mAh/g at 0.1 C. It also has an initial discharge capacity of 774.8 mAh/g measured at 0.5 C and remains 721.8 mAh/g after 100 cycles with a high capacity retention of 93.2%. The outstanding performances are notable in recently reports with modified separator.

关键词: Fe₃C-N-doped reduced graphene oxide, Modified separator, Sulfur cathode, Cyclic and rate performance

Abstract: A new Fe₃C-N-doped reduced graphene oxide (Fe₃C-N-rGO) prepared by a facile method is used as a separator for high performance lithium-sulfur (Li-S) batteries. The Fe₃C-N-rGO is coated on the surface of commercial polypropylene separator (Celgard 2400) close to the sulfur cathode. The special nanotubes are in-situ catalyzed by Fe₃C nanoparticles. They could entrap lithium polysulfides (LiPSs) to restrain the shuttle effect and reduce the loss of active material. The battery with the modified separator and sulfur cathode shows an excellent cycle performance. It has a high rate performance, 580.5 mAh/g at the high current rate of 4 C relative to 1075 mAh/g at 0.1 C. It also has an initial discharge capacity of 774.8 mAh/g measured at 0.5 C and remains 721.8 mAh/g after 100 cycles with a high capacity retention of 93.2%. The outstanding performances are notable in recently reports with modified separator.

Key words: Fe₃C-N-doped reduced graphene oxide, Modified separator, Sulfur cathode, Cyclic and rate performance

Hongyu Pan, Zhong Tan, Haihui Zhou, Lanlan Jiang, Zhongyuan Huang, Qiaoxia Feng, Qiang Zhou, Shuai Ma, Yafei Kuang. Fe₃C-N-doped carbon modified separator for high performance lithium-sulfur batteries[J]. 能源化学(英文版), 2019, 39(12): 101-108.

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Fe₃C-N-doped carbon modified separator for high performance lithium-sulfur batteries

Fe₃C-N-doped carbon modified separator for high performance lithium-sulfur batteries

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