Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl3

能源化学(英文版) ›› 2019, Vol. 39 ›› Issue (12): 268-274.

Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl₃

Jun Chen^a, F. Xu^a, L. Sun^a, Kexiang Zhang^a, Yongpeng Xia^a, Xiaolei Guo^a, Huanzhi Zhang^a, Fang Yu^a, Erhu Yan^a, Hongliang Peng^a, Pengru Huang^a, Shujun Qiu^a, Cuili Xiang^a, Yujie Sun^b

a Guangxi Key Laboratory of Information Materials, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China;
b School of Material Science and Engineering, China University of Geosciences, Beijing 100083, China

收稿日期:2019-01-03 修回日期:2019-03-27 出版日期:2019-12-15 发布日期:2020-12-18
通讯作者: F. Xu, xufen@guet.edu.cn; L. Sun, sunlx@guet.edu.cn
基金资助:
This work was supported by the National Key R&D Program of China (2018YFB1501200, MOST), the National Natural Science Foundation of China (5187011196, U1501242 and 51671062), the Guangxi Collaborative Innovation Centre of Structure and Property for New Energy and Material (2012GXNSFGA06002), Guangxi Science and Technology Project (AD17195073), Guangxi Major Science and Technology Special Project (AA17202030-1) and the Guangxi Key Laboratory of Information Laboratory Foundation (161002-Z, 161002-K and 161003-K). And authors also thank for the financial support of Guangxi Advanced Functional Materials Foundation and Application Talents Small Highlands.

Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl₃

Jun Chen^a, F. Xu^a, L. Sun^a, Kexiang Zhang^a, Yongpeng Xia^a, Xiaolei Guo^a, Huanzhi Zhang^a, Fang Yu^a, Erhu Yan^a, Hongliang Peng^a, Pengru Huang^a, Shujun Qiu^a, Cuili Xiang^a, Yujie Sun^b

a Guangxi Key Laboratory of Information Materials, Guangxi Collaborative Innovation Center of Structure and Property for New Energy and Materials, School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004, Guangxi, China;
b School of Material Science and Engineering, China University of Geosciences, Beijing 100083, China

Received:2019-01-03 Revised:2019-03-27 Online:2019-12-15 Published:2020-12-18
Contact: F. Xu, xufen@guet.edu.cn; L. Sun, sunlx@guet.edu.cn
Supported by:
This work was supported by the National Key R&D Program of China (2018YFB1501200, MOST), the National Natural Science Foundation of China (5187011196, U1501242 and 51671062), the Guangxi Collaborative Innovation Centre of Structure and Property for New Energy and Material (2012GXNSFGA06002), Guangxi Science and Technology Project (AD17195073), Guangxi Major Science and Technology Special Project (AA17202030-1) and the Guangxi Key Laboratory of Information Laboratory Foundation (161002-Z, 161002-K and 161003-K). And authors also thank for the financial support of Guangxi Advanced Functional Materials Foundation and Application Talents Small Highlands.

摘要/Abstract

摘要： In this work, Ni-Bi-B alloy has been synthesized via chemical synthesis method. A new kind of Al-InCl₃-(Ni-Bi-B) composite has been prepared by high energy mechanical ball grinding Al powder with additives. Results show that the doped Ni-Bi-B alloy can significantly improve the hydrogen generation performance of Al-InCl₃ and the catalytic activity is enhanced with the increasing content of Bi in Ni-Bi-B alloy. Under optimal conditions, the hydrogen generation yield and conversion yield of Al-InCl₃-(Ni-Bi-B) reached 1196.8 mL g^-1 and 100.0% at room temperature, respectively. Mechanism study shows five kinds of active sites, such as the fresh surface/defect of Al particle, Al-AlCl₃, Al-In, Al-Bi/B and Al-Ni/B produced during the ball milling process. Their synergistic effect enhances the hydrogen generation performance of AlInCl₃-(Ni-Bi-B) remarkably. In general, the proposed Al-InCl₃-(Ni-Bi-B) composite is possible to serve as hydrogen generation material for fuel cells.

关键词: Hydrogen generation, Al-H₂O reaction, Al-InCl₃, Ni-Bi-B alloy, Ball milling

Abstract: In this work, Ni-Bi-B alloy has been synthesized via chemical synthesis method. A new kind of Al-InCl₃-(Ni-Bi-B) composite has been prepared by high energy mechanical ball grinding Al powder with additives. Results show that the doped Ni-Bi-B alloy can significantly improve the hydrogen generation performance of Al-InCl₃ and the catalytic activity is enhanced with the increasing content of Bi in Ni-Bi-B alloy. Under optimal conditions, the hydrogen generation yield and conversion yield of Al-InCl₃-(Ni-Bi-B) reached 1196.8 mL g^-1 and 100.0% at room temperature, respectively. Mechanism study shows five kinds of active sites, such as the fresh surface/defect of Al particle, Al-AlCl₃, Al-In, Al-Bi/B and Al-Ni/B produced during the ball milling process. Their synergistic effect enhances the hydrogen generation performance of AlInCl₃-(Ni-Bi-B) remarkably. In general, the proposed Al-InCl₃-(Ni-Bi-B) composite is possible to serve as hydrogen generation material for fuel cells.

Key words: Hydrogen generation, Al-H₂O reaction, Al-InCl₃, Ni-Bi-B alloy, Ball milling

Jun Chen, F. Xu, L. Sun, Kexiang Zhang, Yongpeng Xia, Xiaolei Guo, Huanzhi Zhang, Fang Yu, Erhu Yan, Hongliang Peng, Pengru Huang, Shujun Qiu, Cuili Xiang, Yujie Sun. Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl₃[J]. 能源化学(英文版), 2019, 39(12): 268-274.

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Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl₃

Effect of doped Ni-Bi-B alloy on hydrogen generation performance of Al-InCl₃

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