Cryo-induced closely bonded heterostructure for effective CO2 conversion: The case of ultrathin BP nanosheets/g-C3N4

doi:10.1016/j.jechem.2020.01.020

能源化学(英文版) ›› 2020, Vol. 49 ›› Issue (10): 89-95.DOI: 10.1016/j.jechem.2020.01.020

Cryo-induced closely bonded heterostructure for effective CO₂ conversion: The case of ultrathin BP nanosheets/g-C₃N₄

Guli Zhou^a, Jinman Yang^a, Xingwang Zhu^a, Qidi Li^a, Qing Yu^a, Wiam El-alami^a, Chongtai Wang^b, Yuanbin She^c, Junchao Qian^d, Hui Xu^a, Huaming Li^a

a School of Chemistry and Chemical Engineering,Institute for Energy Research,Jiangsu University,Zhenjiang 212013,Jiangsu,China;
b School of Chemistry and Chemical Engineering,Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province,Hainan Normal University,Haikou 571158,Hainan,China;
c State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology,College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China;
d School of Chemistry,Biology and Materials Engineering,Suzhou University of Science and Technology,Suzhou 215009,Jiangsu,China

收稿日期:2019-12-26 修回日期:2020-01-17 出版日期:2020-10-15 发布日期:2020-12-18
通讯作者: Hui Xu, Huaming Li
基金资助:
This study was financially supported by the National Natural Science Foundation of China(21676128,21776118,51902138),Hightech Research Key laboratory of Zhenjiang(SS2018002),Jiangsu Funds for Distinguished Young Scientists(BK20190045),Natural Science Foundation of Jiangsu Province(BK20190835),the Priority Academic Program Development of Jiangsu Higher Education Institutions,Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province(KFKT2019002),Construction funding of High-level teachers,Jiangsu University(4111510008)and the High Performance Computing Platform of Jiangsu University.

Cryo-induced closely bonded heterostructure for effective CO₂ conversion: The case of ultrathin BP nanosheets/g-C₃N₄

Guli Zhou^a, Jinman Yang^a, Xingwang Zhu^a, Qidi Li^a, Qing Yu^a, Wiam El-alami^a, Chongtai Wang^b, Yuanbin She^c, Junchao Qian^d, Hui Xu^a, Huaming Li^a

a School of Chemistry and Chemical Engineering,Institute for Energy Research,Jiangsu University,Zhenjiang 212013,Jiangsu,China;
b School of Chemistry and Chemical Engineering,Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province,Hainan Normal University,Haikou 571158,Hainan,China;
c State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology,College of Chemical Engineering,Zhejiang University of Technology,Hangzhou 310014,Zhejiang,China;
d School of Chemistry,Biology and Materials Engineering,Suzhou University of Science and Technology,Suzhou 215009,Jiangsu,China

Received:2019-12-26 Revised:2020-01-17 Online:2020-10-15 Published:2020-12-18
Contact: Hui Xu, Huaming Li
Supported by:
This study was financially supported by the National Natural Science Foundation of China(21676128,21776118,51902138),Hightech Research Key laboratory of Zhenjiang(SS2018002),Jiangsu Funds for Distinguished Young Scientists(BK20190045),Natural Science Foundation of Jiangsu Province(BK20190835),the Priority Academic Program Development of Jiangsu Higher Education Institutions,Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan Province(KFKT2019002),Construction funding of High-level teachers,Jiangsu University(4111510008)and the High Performance Computing Platform of Jiangsu University.

摘要/Abstract

摘要： Black phosphorus (BP),an interesting and multi-functional non-metal material,has attracted widespread attention.In this work,2D BP/2D g-C₃N₄ heterostructure had been fabricated at extremely low temperature,which was used to reduce CO₂ for the first time.With introduction of 2D BP,the separation of photogenerated holes and electrons was extremely boosted,and composites showed excellent photocatalytic performance (CO₂ to CO).Meanwhile,the targeted composite could keep high selectivity for CO generation and CO generation rate can be up to 187.7 μmol g^-1 h^-1.The formation process of the unique heterostructure and the key factor affecting the photocatalytic performance were also discussed.This work provides a new approach for designing metal free photocatalyst,which is used for CO₂ reduction.

关键词: 2D BP, 2D g-C₃N₄, Heterostructure, CO₂ photoreduction

Abstract: Black phosphorus (BP),an interesting and multi-functional non-metal material,has attracted widespread attention.In this work,2D BP/2D g-C₃N₄ heterostructure had been fabricated at extremely low temperature,which was used to reduce CO₂ for the first time.With introduction of 2D BP,the separation of photogenerated holes and electrons was extremely boosted,and composites showed excellent photocatalytic performance (CO₂ to CO).Meanwhile,the targeted composite could keep high selectivity for CO generation and CO generation rate can be up to 187.7 μmol g^-1 h^-1.The formation process of the unique heterostructure and the key factor affecting the photocatalytic performance were also discussed.This work provides a new approach for designing metal free photocatalyst,which is used for CO₂ reduction.

Key words: 2D BP, 2D g-C₃N₄, Heterostructure, CO₂ photoreduction

Guli Zhou, Jinman Yang, Xingwang Zhu, Qidi Li, Qing Yu, Wiam El-alami, Chongtai Wang, Yuanbin She, Junchao Qian, Hui Xu, Huaming Li. Cryo-induced closely bonded heterostructure for effective CO₂ conversion: The case of ultrathin BP nanosheets/g-C₃N₄[J]. 能源化学(英文版), 2020, 49(10): 89-95.

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Cryo-induced closely bonded heterostructure for effective CO₂ conversion: The case of ultrathin BP nanosheets/g-C₃N₄

Cryo-induced closely bonded heterostructure for effective CO₂ conversion: The case of ultrathin BP nanosheets/g-C₃N₄

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