In situ growth of 3D walnut-like nano-architecture Mo-Ni2P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting

doi:10.1016/j.jechem.2020.02.025

能源化学(英文版) ›› 2020, Vol. 49 ›› Issue (10): 189-197.DOI: 10.1016/j.jechem.2020.02.025

In situ growth of 3D walnut-like nano-architecture Mo-Ni₂P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting

Zhi Yang^a, Yu Lin^a, Feixiang Jiao^a, Jinhui Li^a, Jinlei Wang^a, Yaqiong Gong^a,b

a Chemical Engineering and Technology,North University of China,Taiyuan 030051,Shanxi,China;
b State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,Fujian,China

收稿日期:2020-01-04 修回日期:2020-02-04 出版日期:2020-10-15 发布日期:2020-12-18
通讯作者: Yaqiong Gong
基金资助:
This work is supported financially by the Key Research and Development Program of Shanxi(201803D421085),Shanxi Scholarship Council of China,Shanxi Graduate Education Innovation Project and State key laboratory of physical chemistry of solid surface,Xiamen University(201912).

In situ growth of 3D walnut-like nano-architecture Mo-Ni₂P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting

Zhi Yang^a, Yu Lin^a, Feixiang Jiao^a, Jinhui Li^a, Jinlei Wang^a, Yaqiong Gong^a,b

a Chemical Engineering and Technology,North University of China,Taiyuan 030051,Shanxi,China;
b State Key Laboratory of Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005,Fujian,China

Received:2020-01-04 Revised:2020-02-04 Online:2020-10-15 Published:2020-12-18
Contact: Yaqiong Gong
Supported by:
This work is supported financially by the Key Research and Development Program of Shanxi(201803D421085),Shanxi Scholarship Council of China,Shanxi Graduate Education Innovation Project and State key laboratory of physical chemistry of solid surface,Xiamen University(201912).

摘要/Abstract

摘要： The in situ growth of nano-array on material structure is a novel and high-efficient strategy to design catalysts,however,it still remains a challenge to fabricate unique nano-architecture electrocatalyst with prominent activity and superior durability for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER).Herein,a unique nano-architecture catalyst is successfully synthesized by using NiFe LDH nanosheets as framework to the in situ growth Mo-doped Ni₂P ultrafine nanosheets (marked as Mo-Ni₂P@NiFe LDH/NF).The unique 3D core-shell nano-architecture is favorable for enhancing electron transfer/mass diffusion,providing abundant active sites,prompting O₂/H₂ gas release,and creating the synergistic effect between Mo-Ni₂P and NiFe LDH.Therefore,comparing with pure NiFe LDH/NF and Mo-Ni₂P/NF electrodes,walnut-like Mo-Ni₂P@NiFe LDH/NF catalyst exhibits significantly improved electrocatalytic activities and durability towards OER (269 mV@40 mA cm^-2),HER (82 mV@10 mA cm^-2),and overall water splitting (1.46 V@10 mA cm^-2),respectively.Such electrocatalytic activity of Mo-Ni₂P@NiFe LDH/NF is comparable with that of majority reported non-precious metal catalysts and even precious catalysts (IrO2 and Pt/C).This work presents a new perspective strategy to fabricate ingeniously bifunctional electrocatalysts with well-designed structure and superior performance for clean energy conversion technologies or storage devices.

关键词: Nano-architecture, 3D walnut-like, Synergistic effect, In situ growth, Bifunctional catalyst

Abstract: The in situ growth of nano-array on material structure is a novel and high-efficient strategy to design catalysts,however,it still remains a challenge to fabricate unique nano-architecture electrocatalyst with prominent activity and superior durability for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER).Herein,a unique nano-architecture catalyst is successfully synthesized by using NiFe LDH nanosheets as framework to the in situ growth Mo-doped Ni₂P ultrafine nanosheets (marked as Mo-Ni₂P@NiFe LDH/NF).The unique 3D core-shell nano-architecture is favorable for enhancing electron transfer/mass diffusion,providing abundant active sites,prompting O₂/H₂ gas release,and creating the synergistic effect between Mo-Ni₂P and NiFe LDH.Therefore,comparing with pure NiFe LDH/NF and Mo-Ni₂P/NF electrodes,walnut-like Mo-Ni₂P@NiFe LDH/NF catalyst exhibits significantly improved electrocatalytic activities and durability towards OER (269 mV@40 mA cm^-2),HER (82 mV@10 mA cm^-2),and overall water splitting (1.46 V@10 mA cm^-2),respectively.Such electrocatalytic activity of Mo-Ni₂P@NiFe LDH/NF is comparable with that of majority reported non-precious metal catalysts and even precious catalysts (IrO2 and Pt/C).This work presents a new perspective strategy to fabricate ingeniously bifunctional electrocatalysts with well-designed structure and superior performance for clean energy conversion technologies or storage devices.

Key words: Nano-architecture, 3D walnut-like, Synergistic effect, In situ growth, Bifunctional catalyst

Zhi Yang, Yu Lin, Feixiang Jiao, Jinhui Li, Jinlei Wang, Yaqiong Gong. In situ growth of 3D walnut-like nano-architecture Mo-Ni₂P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting[J]. 能源化学(英文版), 2020, 49(10): 189-197.

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In situ growth of 3D walnut-like nano-architecture Mo-Ni₂P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting

In situ growth of 3D walnut-like nano-architecture Mo-Ni₂P@NiFe LDH/NF arrays for synergistically enhanced overall water splitting

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