Skin care design for lithium metal protection with cosmetics introduction

doi:10.1016/j.jechem.2020.01.036

能源化学(英文版) ›› 2020, Vol. 48 ›› Issue (9): 383-389.DOI: 10.1016/j.jechem.2020.01.036

Skin care design for lithium metal protection with cosmetics introduction

Yurong Tu^a, Qingtao Ma^a, Aoxuan Wang^a, Xinyue Zhang^a, Guojie Li^a,b, Jiayan Luo^a, Xingjiang Liu^a,c

a Key Laboratory for Green Chemical Technology of Ministry of Education.State Key Laboratory of Chemical Engineering.School of Chemical Engineering and Technology.Tianjin University.Tianjin 300072.China;
b Ministry of Education.Key Laboratory of Materials Processing and Mold(Zhengzhou University).Zhengzhou 450002.Henan.China;
c National Key Laboratory of Science and Technology on Power Sources.Tianjin Institute of Power Sources.Tianjin 300384.China

收稿日期:2019-12-21 修回日期:2020-01-23 出版日期:2020-09-15 发布日期:2020-12-18
通讯作者: Aoxuan Wang, Jiayan Luo, Xingjiang Liu
基金资助:
The authors appreciate support from the National Natural Science Foundation of China (Grant nos.51872196),Natural Science Foundation of Tianjin,China (Grant no.17JCJQJC44100),Metal Fuel Cell Key Laboratory of Sichuan Province,National Postdoctoral Program for Innovative Talent (NO.BX20190232) and China Postdoctoral Science Foundation (NO.2019M660059).

Skin care design for lithium metal protection with cosmetics introduction

Yurong Tu^a, Qingtao Ma^a, Aoxuan Wang^a, Xinyue Zhang^a, Guojie Li^a,b, Jiayan Luo^a, Xingjiang Liu^a,c

a Key Laboratory for Green Chemical Technology of Ministry of Education.State Key Laboratory of Chemical Engineering.School of Chemical Engineering and Technology.Tianjin University.Tianjin 300072.China;
b Ministry of Education.Key Laboratory of Materials Processing and Mold(Zhengzhou University).Zhengzhou 450002.Henan.China;
c National Key Laboratory of Science and Technology on Power Sources.Tianjin Institute of Power Sources.Tianjin 300384.China

Received:2019-12-21 Revised:2020-01-23 Online:2020-09-15 Published:2020-12-18
Contact: Aoxuan Wang, Jiayan Luo, Xingjiang Liu
Supported by:
The authors appreciate support from the National Natural Science Foundation of China (Grant nos.51872196),Natural Science Foundation of Tianjin,China (Grant no.17JCJQJC44100),Metal Fuel Cell Key Laboratory of Sichuan Province,National Postdoctoral Program for Innovative Talent (NO.BX20190232) and China Postdoctoral Science Foundation (NO.2019M660059).

摘要/Abstract

摘要： Lithium metal anode (LMA) is the ultimate "Holy Grail" electrode for next generation high-energy-density batteries.Nevertheless.its instinct high reactivity is a formidable challenge and has intensified side reactions.destabilized the electrode/electrolyte interface and restricted the operating conditions strictly.thus hampering its practical application.Here.we "make up" the Li metal (M-Li) by constructing vaselinecoated layer by a simple dip-coating or casting method.With the chemically stable and hydrophobic vaseline protective layer.the stability of Li towards humid and corrosive atmosphere has been greatly improved.The M-Li guaranteed stable and prolonged cycling life after the anode suffering from corrosion in moist air (relative humidity ~65%) or corrosive electrolyte (with 10,000 ppm H₂O or S) both in symmetric cells and LiFePO₄ full cells.This work illustrates a convenient.economic.and industrial applicable method for stable LMA.

关键词: Li metal anode, Interface, Vaseline, Corrosion resistance, Industrial process

Abstract: Lithium metal anode (LMA) is the ultimate "Holy Grail" electrode for next generation high-energy-density batteries.Nevertheless.its instinct high reactivity is a formidable challenge and has intensified side reactions.destabilized the electrode/electrolyte interface and restricted the operating conditions strictly.thus hampering its practical application.Here.we "make up" the Li metal (M-Li) by constructing vaselinecoated layer by a simple dip-coating or casting method.With the chemically stable and hydrophobic vaseline protective layer.the stability of Li towards humid and corrosive atmosphere has been greatly improved.The M-Li guaranteed stable and prolonged cycling life after the anode suffering from corrosion in moist air (relative humidity ~65%) or corrosive electrolyte (with 10,000 ppm H₂O or S) both in symmetric cells and LiFePO₄ full cells.This work illustrates a convenient.economic.and industrial applicable method for stable LMA.

Key words: Li metal anode, Interface, Vaseline, Corrosion resistance, Industrial process

Yurong Tu, Qingtao Ma, Aoxuan Wang, Xinyue Zhang, Guojie Li, Jiayan Luo, Xingjiang Liu. Skin care design for lithium metal protection with cosmetics introduction[J]. 能源化学(英文版), 2020, 48(9): 383-389.

Yurong Tu, Qingtao Ma, Aoxuan Wang, Xinyue Zhang, Guojie Li, Jiayan Luo, Xingjiang Liu. Skin care design for lithium metal protection with cosmetics introduction[J]. Journal of Energy Chemistry, 2020, 48(9): 383-389.

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Skin care design for lithium metal protection with cosmetics introduction

Skin care design for lithium metal protection with cosmetics introduction

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