Doped all-inorganic cesium zirconium halide perovskites with high-efficiency and tunable emission

doi:10.1016/j.jechem.2021.06.033

Abstract

Abstract: Doping enables manipulation of both the electrical and optical properties of halide perovskites. Herein, we incorporated Te⁴⁺ into Cs₂ZrCl₆ single crystal, simultaneously preserving the vacancy-ordered structure, to obtain an efficient yellow-emitting perovskite with a near-unity photoluminescence quantum yield (PLQY ≈ 97.6%). Te⁴⁺ doping modifies the hue and emission color of pristine Cs₂ZrCl₆, generates new absorption channels, and successfully extends the excitation energy from < 280 nm to 360-450 nm range. Detailed spectral characterizations, including ultrafast femtosecond transient absorption measurements, reveal that the bright yellow light is derived from triplet self-trapped excitons. Moreover, further tuning doping concentration enables Te-doped Cs₂ZrCl₆ single crystals to exhibit efficient warm white light emission. This work provides a new perspective for the development and design of stable lead-free perovskites with highly efficient luminescence.

Key words: Zirconium halide perovskite, Doping, Excitation energy, Photoluminescence, Energy transfer

Pengfei Cheng, Daoyuan Zheng, Lu Feng, Yuefeng Liu, Junxue Liu, Juntao Li, Yang Yang, Guoxiong Wang, Keli Han. Doped all-inorganic cesium zirconium halide perovskites with high-efficiency and tunable emission[J]. Journal of Energy Chemistry, 2022, 65(2): 600-604.

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https://www.jenergychem.com/EN/Y2022/V65/I2/600

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