Boosting CO2 hydrogenation to high-value olefins with highly stable performance over Ba and Na co-modified Fe catalyst

doi:10.1016/j.jechem.2023.02.007

Abstract

Abstract: CO₂ hydrogenation has been considered to be a highly promising route for the production of high-value olefins (HVOs) while also mitigating CO₂ emissions. However, it is challenging to achieve high selectivity and maintain stable performance for HVOs (ethylene, propylene, and linear a-olefins) over a prolonged reaction time due to the difficulty in precise control of carbon coupling and rapid catalyst deactivation. Herein, we present a selective Ba and Na co-modified Fe catalyst enriched with Fe₅C₂ and Fe₃C active sites that can boost HVO synthesis with up to 66.1% selectivity at an average CO₂ conversion of 38% for over 500 h. Compared to traditional NaFe catalyst, the combined effect of Ba and Na additives in the NaBaFe-0.5 catalyst suppressed excess oxidation of FeC_x sites by H₂O. The absence of Fe₃O₄ phase in the spent NaBaFe-0.5 catalyst reflects the stabilization effect of the co-modifiers on the FeC_x sites. This study pro-vides a strategy to design Fe-based catalysts that can be scaled up for the stable synthesis of HVOs from CO₂ hydrogenation.

Key words: CO₂ hydrogenation, High-value olefins, Barium additive, Iron carbide, Catalytic stability

Joshua Iseoluwa Orege, Na Liu, Cederick Cyril Amoo, Jian Wei, Qingjie Ge, Jian Sun. Boosting CO₂ hydrogenation to high-value olefins with highly stable performance over Ba and Na co-modified Fe catalyst[J]. Journal of Energy Chemistry, 2023, 80(5): 614-624.

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URL: https://www.jenergychem.com/EN/10.1016/j.jechem.2023.02.007

https://www.jenergychem.com/EN/Y2023/V80/I5/614

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Boosting CO₂ hydrogenation to high-value olefins with highly stable performance over Ba and Na co-modified Fe catalyst

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