Revealing the potential of apparent critical current density of Li/garnet interface with capacity perturbation strategy

doi:10.1016/j.jechem.2022.12.047

Journal of Energy Chemistry ›› 2023, Vol. 79 ›› Issue (4): 56-63.DOI: 10.1016/j.jechem.2022.12.047

Revealing the potential of apparent critical current density of Li/garnet interface with capacity perturbation strategy

Zhihao Guo^a, Xinhai Li^a,b,c, Zhixing Wang^a,b,c, Huajun Guo^a,b,c, Wenjie Peng^a, Guangchao Li^a, Guochun Yan^a,b,c, Qihou Li^a,*, Jiexi Wang^a,b,c,*

^aSchool of Metallurgy and Environment, Central South University, Changsha 410083, Hunan, China;
^bEngineering Research Center of the Ministry of Education for Advanced Battery Materials, Central South University, Changsha 410083, Hunan, China;
^cKey Laboratory of Value-added Metallurgy of Hunan Province, Central South University, Changsha 410083, Hunan, China

Received:2022-11-03 Revised:2022-12-27 Accepted:2022-12-29 Online:2023-04-15 Published:2023-05-30
Contact: * E-mail addresses: liqihou@csu.edu.cn (Q. Li), wangjiexikeen@csu.edu.cn (J. Wang).

Abstract

Abstract: Apparent critical current density (j^a_AC) of garnet all-solid-state lithium metal symmetric cells (ASSLSCs) is a fundamental parameter for designing all-solid-state lithium metal batteries. Nevertheless, how much the possible maximum apparent current density that a given ASSLSC system can endure and how to reveal this potential still require study. Herein, a capacity perturbation strategy aiming to better measure the possible maximum j^a_AC is proposed for the first time. With garnet-based plane-surface structure ASSLSCs as an exemplification, the j^a_AC is quite small when the capacity is dramatically large. Under a per-turbed capacity of 0.001 mA h cm^-2, the j^a_AC is determined to be as high as 2.35 mA cm^-2 at room tem-perature. This investigation demonstrates that the capacity perturbation strategy is a feasible strategy for measuring the possible maximum j^a_AC of Li/ solid electrolyte interface, and hopefully provides good refer-ences to explore the critical current density of other types of electrochemical systems.

Key words: All-solid-state lithium batteries, Li/solid electrolyte interface, Apparent critical current density, Interfacial state variation, Capacity perturbation strategy

Zhihao Guo, Xinhai Li, Zhixing Wang, Huajun Guo, Wenjie Peng, Guangchao Li, Guochun Yan, Qihou Li, Jiexi Wang. Revealing the potential of apparent critical current density of Li/garnet interface with capacity perturbation strategy[J]. Journal of Energy Chemistry, 2023, 79(4): 56-63.

×
share this article

Add to citation manager EndNote|Ris|BibTeX

URL: https://www.jenergychem.com/EN/10.1016/j.jechem.2022.12.047

https://www.jenergychem.com/EN/Y2023/V79/I4/56

References

[1] M. Balaish, J.C. Gonzalez-Rosillo, K.J. Kim, Y. Zhu, Z.D. Hood, J.L.M. Rupp, Nat. Energy 6(2021) 227-239.
[2] D. Gu, H. Kim, J.-H.Lee, S. Park, J. Energy Chem. 70(2022) 248-257.
[3] P. Albertus, V. Anandan, C. Ban, N. Balsara, I. Belharouak, J. Buettner-Garrett, Z. Chen, C. Daniel, M. Doeff, N.J. Dudney, B. Dunn, S.J. Harris, S. Herle, E. Herbert, S. Kalnaus, J.A. Libera, D. Lu, S. Martin, B.D.McCloskey, M.T.McDowell, Y.S. Meng, J. Nanda, J. Sakamoto, E.C. Self, S. Tepavcevic, E. Wachsman, C. Wang, A.S. Westover, J. Xiao, T. Yersak, ACS Energy Lett. 6(2021) 1399-1404.
[4] L. Xu, J. Li, H. Shuai, Z. Luo, B. Wang, S. Fang, G. Zou, H. Hou, H. Peng, X. Ji, J. Energy Chem. 67(2022) 524-548.
[5] A. Sharafi, H.M. Meyer, J. Nanda, J. Wolfenstine, J. Sakamoto, J. Power Sources 302(2016) 135-139.
[6] Y. Lu, C.-Z.Zhao, H. Yuan, X.-B. Cheng, J.-Q. Huang, Q. Zhang, Adv. Funct. Mater. 31(2021) 2009925.
[7] F. Han, J. Yue, X. Zhu, C. Wang, Adv. Energy Mater. 8(2018) 1703644.
[8] Z. Tian, D. Kim, J. Energy Chem. 68(2022) 603-611.
[9] Y. Ye, X. Ye, H. Zhu, J. Bian, H. Lin, J. Zhu, Y. Zhao, J. Energy Chem.(2022), https://doi.org/10.1016/j.jechem.2022.10.037.
[10] Y. Huang, B. Chen, J. Duan, F. Yang, T. Wang, Z. Wang, W. Yang, C. Hu, W. Luo, Y.Huang, Angew. Chem. Int. Ed. 59(2020) 3699-3704.
[11] A. Sharafi, E. Kazyak, A.L. Davis, S. Yu, T. Thompson, D.J. Siegel, N.P. Dasgupta, J. Sakamoto, Chem. Mater. 29(2017) 7961-7968.
[12] X. Huang, Y. Lu, H. Guo, Z. Song, T. Xiu, M.E. Badding, Z. Wen, A.C.S.Appl, Energy Mater. 1(2018) 5355-5365.
[13] C.-L. Tsai, V. Roddatis, C.V. Chandran, Q. Ma, S. Uhlenbruck, M. Bram, P. Heitjans, O. Guillon, A.C.S. Appl, Mater. Interfaces 8(2016) 10617-10626.
[14] R. Hongahally Basappa, T. Ito, T. Morimura, R. Bekarevich, K. Mitsuishi, H. Yamada, J. Power Sources 363(2017) 145-152.
[15] M. Cai, Y. Lu, J. Su, Y. Ruan, C. Chen, B.V.R. Chowdari, Z. Wen, A.C.S. Appl, Mater. Interfaces 11(2019) 35030-35038.
[16] Y. Ruan, Y. Lu, X. Huang, J. Su, C. Sun, J. Jin, Z. Wen, J. Mater. Chem. A 7(2019) 14565-14574.
[17] Y. Song, L. Yang, W. Zhao, Z. Wang, Y. Zhao, Z. Wang, Q. Zhao, H. Liu, F. Pan, Adv. Energy Mater. 9(2019) 1900671.
[18] J. Lou, G. Wang, Y. Xia, C. Liang, H. Huang, Y. Gan, X. Tao, J. Zhang, W. Zhang, J. Power Sources 448(2020).
[19] J. Meng, Y. Zhang, X. Zhou, M. Lei, C. Li, Nat. Commun. 11(2020) 3716.
[20] K. Lee, S. Han, J. Lee, S. Lee, J. Kim, Y. Ko, S. Kim, K. Yoon, J.-H.Song, J.H. Noh, K. Kang, ACS Energy Lett. 7(2022) 381-389.
[21] M. Suyama, A. Kato, A. Sakuda, A. Hayashi, M. Tatsumisago, Electrochim. Acta 286(2018) 158-162.
[22] Z. Zhang, L. Zhang, X. Yan, H. Wang, Y. Liu, C. Yu, X. Cao, L. van Eijck, B.Wen, J. Power Sources 410-411(2019) 162-170.
[23] R. Zhao, S. Kmiec, G. Hu, S.W. Martin, A.C.S. Appl, Mater. Interfaces 12(2020) 2327-2337.
[24] N.J. Taylor, S. Stangeland-Molo, C.G. Haslam, A. Sharafi, T. Thompson, M. Wang, R. Garcia-Mendez, J. Sakamoto, J. Power Sources 396(2018) 314-318.
[25] M. Wang, J.B. Wolfenstine, J. Sakamoto, Electrochim. Acta 296(2019) 842-847.
[26] Y. Lu, X. Huang, Y. Ruan, Q. Wang, R. Kun, J. Yang, Z. Wen, J. Mater. Chem. A 6(2018) 18853-18858.
[27] M.J. Wang, R. Choudhury, J. Sakamoto, Joule 3(2019) 2165-2178.
[28] J.-M.Doux, H. Nguyen, D.H.S. Tan, A. Banerjee, X. Wang, E.A. Wu, C. Jo, H. Yang, Y.S. Meng, Adv. Energy Mater. 10(2020) 1903253.
[29] X. Zhang, Q.J. Wang, K.L. Harrison, S.A. Roberts, S.J. Harris,Cell Rep. Phys. Sci. 1(2020).
[30] R. Xu, F. Liu, Y. Ye, H. Chen, R.R. Yang, Y. Ma, W. Huang, J. Wan, Y. Cui, Adv. Mater. 33(2021) 2104009.
[31] K. Fu, Y. Gong, G.T. Hitz, D.W.McOwen, Y. Li, S.Xu, Y. Wen, L. Zhang, C. Wang, G. Pastel, J. Dai, B. Liu, H. Xie, Y. Yao, E.D. Wachsman, L. Hu, Energy Environ. Sci. 10(2017) 1568-1575.
[32] S. Xu, D.W.McOwen, C. Wang, L.Zhang, W. Luo, C. Chen, Y. Li, Y. Gong, J. Dai, Y. Kuang, C. Yang, T.R. Hamann, E.D. Wachsman, L. Hu, Nano Lett. 18(2018) 3926-3933.
[33] G.T. Hitz, D.W. McOwen, L. Zhang, Z. Ma, Z. Fu, Y. Wen, Y. Gong, J. Dai, T.R. Hamann, L. Hu, E.D. Wachsman, Mater. Today 22(2019) 50-57.
[34] V. Thangadurai, W. Weppner, Adv. Funct. Mater. 15(2005) 107-112.
[35] G.V. Alexander, S. Patra, S.V. Sobhan Raj, M.K. Sugumar, M.M. Ud Din, R. Murugan, J. Power Sources 396(2018) 764-773.
[36] K. Fu, Y. Gong, B. Liu, Y. Zhu, S. Xu, Y. Yao, W. Luo, C. Wang, S.D. Lacey, J. Dai, Y. Chen, Y. Mo, E. Wachsman, L. Hu, Sci. Adv. 3(2017) e1601659.
[37] T. Wang, J. Duan, B. Zhang, W. Luo, X. Ji, H. Xu, Y. Huang, L. Huang, Z. Song, J. Wen, C. Wang, Y. Huang, J.B. Goodenough, Energy Environ. Sci. 15(2022) 1325-1333.
[38] W. Chang, R. May, M. Wang, G. Thorsteinsson, J. Sakamoto, L. Marbella, D. Steingart, Nat. Commun. 12(2021) 6369.
[39] J. Lin, L. Wu, Z. Huang, X. Xu, J. Liu, J. Energy Chem. 40(2020) 132-136.

Revealing the potential of apparent critical current density of Li/garnet interface with capacity perturbation strategy

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

share this article

References

Related Articles 5

Recommended Articles

Metrics

[1]	Lifan Wang, Leiying Wang, Qinlin Shi, Cong Zhong, Danya Gong, Xindong Wang, Chun Zhan, Guicheng Liu. In-situ constructed SnO₂ gradient buffer layer as a tight and robust interphase toward Li metal anodes in LATP solid state batteries [J]. Journal of Energy Chemistry, 2023, 80(5): 89-98.
[2]	Jaeyoung Kim, Wontae Lee, Jangwhan Seok, Eunkang Lee, Woosung Choi, Hyunyoung Park, Soyeong Yun, Minji Kim, Jun Lim, Won-Sub Yoon. Inhomogeneous lithium-storage reaction triggering the inefficiency of all-solid-state batteries [J]. Journal of Energy Chemistry, 2022, 66(3): 226-236.
[3]	Jingguang Yi, Dan Zhou, Yuhao Liang, Hong Liu, Haifang Ni, Li-Zhen Fan. Enabling high-performance all-solid-state lithium batteries with high ionic conductive sulfide-based composite solid electrolyte and ex-situ artificial SEI film [J]. Journal of Energy Chemistry, 2021, 58(7): 17-24.
[4]	Jingguang Yi, Pingge He, Hong Liu, Haifang Ni, Zhiming Bai, Li-Zhen Fan. Manipulating interfacial stability of LiNi_0.5Co_0.3Mn_0.2O₂ cathode with sulfide electrolyte by nanosized LLTO coating to achieve high-performance all-solid-state lithium batterie [J]. Journal of Energy Chemistry, 2021, 52(1): 202-209.
[5]	Xuelei Li, Huilan Guan, Zhijie Ma, Ming Liang, dawei Song, Hongzhou Zhang, Xixi Shi, chunliang Li, Lifang Jiao, Lianqi Zhang. In/ex-situ Raman spectra combined with EIS for observing interface reactions between Ni-rich layered oxide cathode and sulfide electrolyte [J]. Journal of Energy Chemistry, 2020, 48(9): 195-202.