Journal of Energy Chemistry ›› 2023, Vol. 86 ›› Issue (11): 180-196.DOI: 10.1016/j.jechem.2023.07.005

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Plasma-based CO2 conversion: How to correctly analyze the performance?

Bart Wantena,*, Rani Vertongena, Robin De Meyera,b, Annemie Bogaertsa,*   

  1. aResearch Group PLASMANT, Department of Chemistry, University of Antwerp, Universiteitsplein 1, 2610 Antwerp, Belgium;
    bResearch group EMAT, Department of Physics, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium
  • Received:2023-04-28 Revised:2023-06-16 Accepted:2023-07-02 Online:2023-11-15 Published:2023-11-07
  • Contact: *E-mail addresses: bart.wanten@uantwerpen.be (B. Wanten), annemie.bogaerts@uantwerpen.be (A. Bogaerts).
  • About author:1These authors contributed equally to this work.

Abstract: Plasma-based CO2 conversion is promising for carbon capture and utilization. However, inconsistent reporting of the performance metrics makes it difficult to compare plasma processes systematically, complicates elucidating the underlying mechanisms and compromises further development of this technology. Therefore, this critical review summarizes the correct definitions for gas conversion in plasma reactors and highlights common errors and inconsistencies observed throughout literature. This is done for pure CO2 splitting, dry reforming of methane and CO2 hydrogenation. We demonstrate that the change in volumetric flow rate is a critical aspect, inherent to these reactions, that is often not correctly taken into account. For dry reforming of methane and CO2 hydrogenation, we also demonstrate inconsistent reporting of energy efficiency, and through numerical examples, we show the significance of these deviations. Furthermore, we discuss how to measure changes in volumetric flow rate, supported by data from two experimental examples, showing that the sensitivity inherent to a standard component and a flow meter is essential to consider when deriving the performance metrics. Finally, some general recommendations and good practices are provided. This paper aims to be a comprehensive guideline for authors, to encourage more consistent calculations and stimulate the further development of this technology.

Key words: Plasma, CO2, Dry reforming of methane, CO2 hydrogenation, Conversion, Performance